Preconcentration and speciation of chromium using a melamine based polymeric sequestering succinic acid resin: its application for Cr(VI) and Cr(III) determination in wastewater


Dogutan M., Filik H. , Tor I.

TALANTA, cilt.59, sa.5, ss.1053-1060, 2003 (SCI İndekslerine Giren Dergi) identifier identifier

Özet

A new melamine based polymeric sequestering resin was prepared for preconcentration and separation of hexavalent chromium from water, and its sequestering action was investigated. The water-insoluble, cross-linked sequestering resin was formed by reaction with bromosuccinic acid and cross-linking of melamine. The active sequestering group on the resin is -NH-(Succinic acid) or salt thereof. The resulting chelating resin was characterized by infrared spectra. The newly prepared resin quantitatively retained Cr(VI) at pH 2.0-4.0 when the flow rate was maintained between 1 and 5 ml min(-1). The retained Cr(VI) was instantaneously eluted with 25 ml of 0.1 M NaOH. The chromium species were determined by a flame atomic absorption spectrometer. The limits of detection for Cr(VI) and Cr(III) were found to be 5.3 and 4.2 mug 1(-1), respectively. The precision and accuracy of the proposed procedure was checked by the use synthetic and reference steel samples. The established preconcentration method was successfully applied to the determination and selective separation of Cr(VI) in electroplating industry wastewater. Total concentrations determined by the spectrophotometric method (110.3+/-0.6 g 1(-1) Cr(VI) and 1.2+/-0.3 g 1(-1) Cr(III)) are compared with those found by FAAS and the obtained results (110.4+/-1.8 g 1(-1) Cr(VI) and 1.4+/-0.5 g 1(-1) Cr(III)) show good agreement. (C) 2003 Published by Elsevier Science B.V.