New Piperazine Derivatives Synthesized from Thio-Substituted Polyhalogeno-2-nitro-1,3-butadienes


Creative Commons License

Aydinli S. G. , Ibis C.

E-JOURNAL OF CHEMISTRY, cilt.7, ss.1498-1506, 2010 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 7 Konu: 4
  • Basım Tarihi: 2010
  • Doi Numarası: 10.1155/2010/605760
  • Dergi Adı: E-JOURNAL OF CHEMISTRY
  • Sayfa Sayıları: ss.1498-1506

Özet

It is known that polyhalogeno-nitro-1,3-butadienes are important starting materials for the synthesis of polyfunctionalized bioactive heterocycles. Novel N, S-substituted nitrobutadienes (4a-j) were synthesized from the reaction of the monothio-substituted nitrodiene derivatives (2a) and (2b) with some piperazine derivatives. These new compounds are stable and the structures of these products were characterized by spectroscopic data. The structure of the novel N, S-substituted nitrodiene compound (4g) synthesized in this study was also elucidated by single crystal x-ray analysis.