Reaktionen von 2-nitro-polyhalodienen mit s, s-, o, s- und n, s-nucleophilen zu 1, 3-ox athiol an-, 1, 3-thiazolidin, 1, 3-dithian- und thioetherverbindungen


Ibiş C. , SAYIL M. Ç.

Phosphorus, Sulfur, and Silicon and the Related Elements, cilt.106, ss.29-36, 1995 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 106
  • Basım Tarihi: 1995
  • Doi Numarası: 10.1080/10426509508027886
  • Dergi Adı: Phosphorus, Sulfur, and Silicon and the Related Elements
  • Sayfa Sayıları: ss.29-36

Özet

2-Nitro-1,3-butadiene (1) has yielded 1,3-Oxathiolane when reacted with HS-CH2-CH2-OH in Ethanol in the presence of NaOH. Mono(thio)substituted butadiene compounds 4a-c and 4i were obtained from 1 and thiols (3a-c, 3i). 2-Nitroperhalo-1,3-butadiene (5), when reacted with (3c-t) thiols, gave compounds 7c-l and 8e. 1,3-Thiazolidine 6 was obtained from the reaction of 2-amino-ethanol hydrochloride with compound 5 in the presence of ethanol and sodium hydroxide. Compounds 9, 10 and 11 were obtained by stirring of the compound 5 with an ethanolthiol for a long time. 1,3-Dithiane compound 15 with a heterocyclic structure and thioether compounds 13 and 14 were also obtained from the reaction of 1 with dithiols.