The novel N,S-substituted halonitrodienes from the reactions of thiosubstituted nitrodiene with piperazine and morpholine


Ibis C. , Onul N.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.180, ss.2787-2792, 2005 (SCI İndekslerine Giren Dergi)

  • Cilt numarası: 180 Konu: 12
  • Basım Tarihi: 2005
  • Doi Numarası: 10.1080/104265090968163
  • Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  • Sayfa Sayısı: ss.2787-2792

Özet

The substituted 1,2-dibromomethanethio nitrodiene 2 was obtained from the addition of bromine to S-substituted nitrodien 1 in carbon tetrachloride. N,S-substituted compounds 4a-h were synthesized from the reactions of compound 2 with several substituted piperazine derivatives 3a-h in dichloromethane. N,S-substituted compounds 6 and 8 were synthesized from the reaction of 2 with morpholine (5) and thiomorpholine (7) in dichloromethane, respectively. Dibutadienyl piperazines 10, 12, and 14 were synthesized from the reactions of 2 with homopiperazine (9), piperazine (11), and 2,5-dimethylpiperazine (13), respectively.