The synthesis and characterization of novel quinone-amine polymers from the reactions of 2,3-dichloro-1,4-naphthoquinone and polyoxypropylenediamines


Ayla S. , Bahar H., Yavuz S., Hazer B., Ibis C.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.191, ss.438-443, 2016 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 191 Konu: 3
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1080/10426507.2015.1100187
  • Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  • Sayfa Sayıları: ss.438-443

Özet

A series of novel N- and N,N'-bis(quinonyl)amines were synthesized from the reactions of 2,3-dichloro-1,4-naphthoquinone (1) and polyoxypropylenediamines. The novel quinone-amine polymers were treated with some thiols in next step and N,S- substituted compounds were obtained. The structures of the novel products were characterized by micro-analysis, H-1 NMR, UV-VIS, C-13 NMR, and MS. The electrochemical properties of some of the novel amine-quinone polymers derivatives were also investigated by cyclic voltammetry. The number of molecular weight (Mn) of polymer compounds was also determined by Gel Permeation Chromatography (GPC).