Vanadium(III) chloride complexes of 1,2-bis-(5-H/methyl/chloro/nitro-1H-benzimidazol-2-yl)-1,2-ethanediols


Tavman A.

JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, cilt.71, ss.521-528, 2006 (SCI İndekslerine Giren Dergi)

  • Cilt numarası: 71 Konu: 5
  • Basım Tarihi: 2006
  • Doi Numarası: 10.2298/jsc0605521t
  • Dergi Adı: JOURNAL OF THE SERBIAN CHEMICAL SOCIETY
  • Sayfa Sayısı: ss.521-528

Özet

The complexes of 1,2-bis-(5-H/methyl/chloro/nitro-1H-benzimidazol-2-yl)-1,2-ethanediols (L1-L4) with VCl3 were synthesized and characterized by elemental analyses, molar conductivity, FTIR and H-1-NMR spectroscopy. The ligands act as bidentate coordinating through both of the hydroxyl group oxygen atoms in the complexes, The ionic and diamagnetic complexes have the empirical formula [V(L)(2)]Cl-3. The [V(L-4)(2)]Cl-3 complex has two isomeric structures according to the H-1-NMR spectral data.