SYNTHESIS OF NOVEL THIOETHERS AND SULFOXIDE COMPOUNDS


Ibis C., Ayla S. , Beyazit N., Bahar H.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.188, ss.1643-1651, 2013 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 188 Konu: 11
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1080/10426507.2012.757610
  • Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
  • Sayfa Sayıları: ss.1643-1651

Özet

Thiosubstituted butadiene and butenyne compounds were synthesized from the reactions of 1,1,3,3,4,4-hexachloro-1-butene or 1,1,2,4,4-pentachlorobuta-1,3-diene with different thiols in EtOH/H2O solution of NaOH. Tris(thio)substituted butadiene compound was treated with potassium tert-butoxide to obtain tris(thio)substituted butatrienyl halide compound. The novel sulfoxide compounds were synthesized from the reactions of polyhalobutadiene compounds with aliphatic thiols in CHCl3 with m-CPBA at 0 degrees C. The structures of the novel compounds were characterized by micro analysis, FT-IR, H-1-NMR, C-13-NMR, and MS.